“The earth is bountiful, and where her bounty fails, nitrogen drawn from the air will refertilize her womb.”*…

As the Iran War continues to unfold, there is understandably a great deal of concern about energy prices (and the prices of things that depend on energy). We might forget that the Middle East is also crucial to the world’s fertilizer supply– though not for long, as farmers (along with everyone else in the food chain, all the way down to all of us eaters) are beginning to feel the pain.

But, as Diana Kruzman reports, even as fertilizer trade concerns are growing, a revolutionary sourcing alternative has emerged– one that could make a huge positive difference if it proves out at scale…

The world has an almost insatiable demand for nitrogen. Crops need it to grow, but although it makes up 78 percent of our atmosphere, plants can’t just pull it in from the air the way they do with oxygen. Instead, they rely on bacteria in the soil to convert it into nitrate, a form they can use; in the case of agriculture, think of fertilizer spread by humans. Leaving aside organic options like cow manure, most farmers use ammonia produced mainly from natural gas using a technique called the Haber-Bosch process, which was invented in 1909. [See also here.]

Haber-Bosch is expensive and energy-intensive, responsible for up to two percent of the world’s annual greenhouse gas emissions. It’s also spurred a global nitrogen pollution crisis; as much as two-thirds of nitrogen fertilizer applied to crops is never used, and the excess escapes into the soil, air, and water, raising the cancer risk in nearby communities and contributing to climate change.

Researchers have been trying to find an alternative way to get nitrogen to plants for decades — turning to everything from microbes to human urine. But so far, these scientific advancements haven’t translated into much practical change for farmers, who for the most part still rely on ammonia (which, granted, is getting greener, but is increasingly vulnerable to global price shocks).

That could soon change with the growth in popularity of a new technology known as plasma activated water, or PAW. Around the U.S., scientists and startups are experimenting with this high-tech solution, which uses electricity to pull nitrogen from the air, mix it with water, and create fertilizer straight on the farm. The concept, on the surface, seems suspiciously rosy — on-demand nitrogen, in a form plants can use, at just the cost of electricity (and the initial price of the machine used to make it). But early adopters have told Offrange that it genuinely works…

… PAW uses electricity to transform air into plasma — the fourth state of matter (besides gases, solids, and liquids), which typically forms at high temperatures. When the plasma comes into contact with water, it encourages chemical reactions that form nitrates — the type of nitrogen that plants need. Though this process was actually invented in 1903, even before Haber-Bosch, it required so much energy that it never achieved widespread use.

But in recent years, those energy needs have gone down thanks to the development of “cold plasma” technology, which operates at less than 60 degrees Fahrenheit. It’s also used for medical sterilization and food safety, and over the last decade researchers have worked to develop new ways to apply it for agricultural production…

More at: “Pulling Nitrogen From the Air” from @dkruzman.bsky.social.

* Nikola Tesla (who, around 1900, imagined and experimented with something like the Birkeland–Eyde-based plasma process described above)

###

As we count on creativity, we might send healthy birthday greetings to a man who explained one of the central ways in which we depend on the food that we eat, William Cumming Rose; he was born on this date in 1887. A biochemist, he researched amino acids, discovered threonine, and established the importance of the nine essential amino acids in human nutrition (that’s to say, the amino acids that our bodies cannot synthesize and that we must consume in our food). He received the National Medal of Science in 1966.

source

#agriculture #aminoAcid #aminoAcids #biochemistry #culture #farming #fertilizer #history #MiddleEast #NikolaTesla #nitrogen #nutrition #Science #Technology #war #WilliamCummingRose #WilliamRose

Scientists were able to extract the protein collagen from preserved blood vessel structures recovered from the cortical bone of a Tyrannosaurus rex.

https://www.nature.com/articles/s41598-019-51680-1

#tyrannosaurusrex #tyrannosaurus #dinosaur #dinosaurs #palaeontology #fossil #paleontology #science #sciencenews #evolution #protein #collagen #trex #jurassicpark #biology #biochemistry

Mechanisms of soft tissue and protein preservation in Tyrannosaurus rex - Scientific Reports

The idea that original soft tissue structures and the native structural proteins comprising them can persist across geological time is controversial, in part because rigorous and testable mechanisms that can occur under natural conditions, resulting in such preservation, have not been well defined. Here, we evaluate two non-enzymatic structural protein crosslinking mechanisms, Fenton chemistry and glycation, for their possible contribution to the preservation of blood vessel structures recovered from the cortical bone of a Tyrannosaurus rex (USNM 555000 [formerly, MOR 555]). We demonstrate the endogeneity of the fossil vessel tissues, as well as the presence of type I collagen in the outermost vessel layers, using imaging, diffraction, spectroscopy, and immunohistochemistry. Then, we use data derived from synchrotron FTIR studies of the T. rex vessels to analyse their crosslink character, with comparison against two non-enzymatic Fenton chemistry- and glycation-treated extant chicken samples. We also provide supporting X-ray microprobe analyses of the chemical state of these fossil tissues to support our conclusion that non-enzymatic crosslinking pathways likely contributed to stabilizing, and thus preserving, these T. rex vessels. Finally, we propose that these stabilizing crosslinks could play a crucial role in the preservation of other microvascular tissues in skeletal elements from the Mesozoic.

Nature
Associate Research Scientist

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