#eudev upgrade would introduce an extensible database of devices, called "hwdb". When adding new devices, such as with upower, you are supposed to add them to /usr/lib/udev/hwdb.d/ and then run udevadm hwdb --update, to compile the database down to a hwdb.bin file.
However, this does not fit well the #guix way, where each package has its own ro-mounted /usr.