There's a guy on TinkerDifferent that got their hands on an early prototype of the Finder from 1982 and some other early demo apps - including the Bouncing Pepsi Caps (made to impress mike scully) app.
MacPaint 0.1, the IconEditor and a few others. This is all stuff the Mac team was using to build the Mac. Pretty cool! I don't think any of these apps were outside Apple until now?