@patrick_h_lauke This almost certainly is caused by the (color profile of the) monitor you're using.
I can't replicate it on my (stock) windows machine with Chrome's eyedropper running in Polypane.
Indeed: If color management is enabled (on any system, Win/Mac/Lix) the dropper may provide unpredictable results. Choosing a default sRGB profile while using the picker may help mitigate issues.
Better to use a stand alone dropper tool that is color management aware.
For MacOS, that's "Classic Color Meter" desktop app.
Discussion and best practices in our draft guidelines:
https://readtech.org/ARC/tests/visual-readability-contrast/?tn=methods#tool-setup