Carboranyl Diphosphine Activates Ammonia

Metal-free, room-temperature N–H bond activation

https://www.chemistryviews.org/carboranyl-diphosphine-activates-ammonia/

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Carboranyl Diphosphine Activates Ammonia - ChemistryViews

Metal-free, room-temperature N–H bond activation

ChemistryViews

Electron Delocalization across a Carborane Bridge

Monoanionic cluster shows unprecedented communication between the boron centers of opposing substituents

https://www.chemistryviews.org/electron-delocalization-across-a-carborane-bridge/

#delocalization #carboranes #inorgchem #inorganicchemistry #chemistry #chemistryviews

Electron Delocalization across a Carborane Bridge - ChemistryViews

Monoanionic cluster shows unprecedented communication between the boron centers of opposing substituents

ChemistryViews

Carborane-Fused Boron Heterocycles:

Pd-catalyzed process connects different NH-heterocycles, anilines, or heteroanilines to neighboring boron centers of a carborane

https://www.chemistryviews.org/carborane-fused-boron-heterocycles/

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Carborane-Fused Boron Heterocycles - ChemistryViews

Pd-catalyzed path connects nitrogen-functionalized heterocycles with neighboring boron centers of a carborane cluster

ChemistryViews

Popular this week: Direct B–H Functionalization of Icosahedral Carboranes
Work by Deshuang Tu, Chang-Sheng Lu, Hong Yan, Nanjing University, China, and colleagues

https://www.chemistryviews.org/direct-b-h-functionalization-of-icosahedral-carboranes/

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Direct B–H Functionalization of Icosahedral Carboranes - ChemistryViews

Strategy based on nitrogen-centered radical-mediated hydrogen atom transfer (HAT)

ChemistryViews