As your user account, just run something like:
podman volume export VOLUME >backup.tar
Or from another machine, say you want to do a remote backup from your server:
ssh user@host podman volume export VOLUME | zstd -o backup.tar.zstd
Most VPNs don’t allow port forwarding, and if they do it’s a random port that changes frequently. So you’d need a method to tell people the new port. Also, you typically want to use SSL so you’ll have to use self signed certs. Though interestingly LetsEncrypt recently started testing certs for IP addresses:

Since Let’s Encrypt started issuing certificates in 2015, people have repeatedly requested the ability to get certificates for IP addresses, an option that only a few certificate authorities have offered. Until now, they’ve had to look elsewhere, because we haven’t provided that feature. Today, we’ve issued our first certificate for an IP address, as we announced we would in January. As with other new certificate features on our engineering roadmap, we’ll now start gradually rolling out this option to more and more of our subscribers.