For any prime p there are exactly two non-abelian groups of order p³:
1. The Heisenberg group of the field with the p elements, which consists of matrices of the form
[1 a c]
[0 1 b]
[0 0 1]
with a, b, c in Fₚ.
2. The semidirect product Z/p² ⋊ Z/p with Z/p acting on Z/p² via a·x := (1+ap)x.
Those two non-isomorphic groups have isomorphic character tables!
What are some other nice examples of infinite families of groups with isomorphic character tables?