It's coming out on PC which supports modding and VR. It's not the same thing that's true but Starfield will receive heavy mod support and a decent VR experience is almost a given on PC eventually in my opinion.
I had a PSVR and Skyrim was easily my favorite experience on the system despite how lacking the hardware was. I had high hopes Bethesda could actually deliver some really top-quality VR games across the whole of the VR market, but Microsoft has obviously dashed those.